Diplatinum Complexes with Bridging Silyl Ligands. Si−H Bond Activation of μ-Silyl Ligand Leading to a New Platinum Complex with Bridging Silylene and Silane Ligands
Author:
Affiliation:
1. Chemical Resources Laboratory (R1-3), Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om060930c
Reference30 articles.
1. Platinum−Silicon Four-Membered Rings of Two Different Structural Types
2. Reaction of a Symmetrical Diplatinum Complex Containing Bridging μ-η2-H−SiH(IMP) Ligands (IMP = 2-Isopropyl-6-methylphenyl) with PMe2Ph. Formation and Characterization of {(PhMe2P)2Pt[μ-SiH(IMP)]}2
3. Synthesis and Characterization of Diplatinum Complexes Containing Bridging μ-η2-H−SiHAr Ligands. X-ray Crystal Structure Determination of {(Ph3P)Pt[μ-η2-H−SiHAr]}2 (Ar = 2,4,6-(CF3)3C6H2, C6Ph5)
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