Unusual Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Reactive Salts [Et3NH][(μ-CO)(μ-RS)Fe2(CO)6]. A Route to Dimetal Bridging Carbene Complexes-Reference-Cited by-同舟云学术

Unusual Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Reactive Salts [Et3NH][(μ-CO)(μ-RS)Fe2(CO)6]. A Route to Dimetal Bridging Carbene Complexes

Published:1998-01-28 Issue:4 Volume:17 Page:600-606
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Qiu Zhilei¹,Sun Jie¹,Chen Jiabi¹

Affiliation:

1. Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9706267

Reference25 articles.

1. Unusual reaction between a cationic carbyne complex of rhenium and nucleophiles containing a carbonyliron dianion to form a dimetal complex with a bridging carbene ligand. Syntheses and crystal structures of [.eta.-C5H5(CO)2Re(.mu.-CHC6H5)Fe(CO)4], [.eta.-C5H5(CO)2Re:C(OC2H5)C6H5], and [.eta.-C5H5(CO)2BrReCH2C6H5]

2. Unusual reactions of a cationic carbyne complex of manganese with carbonyliron dianions to form a novel dimetal carbene-bridged complex [MnFe{µ-C(COEt)Ph}(η-C5H5)(CO)5]

3. A general route to novel dinuclear iron carbonyl complexes containing alkanethiolate and bridging organic ligands

4. Novel C-alkylation of a CO-bridged dinuclear iron carbonyl anion: a new synthesis of Fe2(CO)6 complexes containing a bridging acyl ligand

5. Synthesis and reactivity of (μ-σ,π-acetylide) (μ-alkane- and μ-arene-thiolate)bis(tricarbonyliron) complexes

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