Mechanistic Study of β-Methyl and β-Hydrogen Elimination in the Zirconocene Compounds Cp‘2ZrR(μ-CH3)B(C6F5)3 (Cp‘ = Cp, Cp*; R = CH2CMe3, CH2CHMe2)

Author:

Yang Ping1,Baird Michael C.1

Affiliation:

1. Department of Chemistry, Queen's University, Kingston, Ontario K7L 3N6, Canada

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference35 articles.

1. For useful reviews see:  (a) Möhring, P. C.; Coville, N. J.J. Organomet.Chem.1994,479, 1. (b) Gupta, V. K.; Satish, S.; Bhardwaj, I. S.J. Macromol.Sci., Rev. Macromol. Chem. Phys.1994,C34, 439. (c) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B. Waymouth, R. M.Angew. Chem., Int.Ed. Engl.1995,34, 1143. (d) Bochmann, M.J Chem. Soc., Dalton Trans.1996, 255. (e) Kaminsky, W.; Arndt, M.Adv. Polym. Sci.1997,127, 143. (f) Chien, J. C. W. InTopics in Catalysis; Marks, T. J., Stevens, J. C., Eds.; Baltzer AG, Science Publishers, 1999; Vol. 7, p 23. (g) Alt, H. G.; Köppl, A.Chem. Rev.2000,100, 1205. (h) Coates, G. W.Chem. Rev.2000,100, 1223. (i) Resconi, L.; Cavallo, L.; Fait, A.; Piemontesi, F.Chem. Rev.2000,100, 1253. (j) Angermund, K.; Fink, G.; Jensen, V. R.; Kleinschmidt, R.Chem.Rev.2000,100, 1457. (k) Scheirs J., Kaminsky, W., Eds.Metallocene-basedPolyolefins; John Wiley and Sons:  U.K, 1999. (l) Chen, E. Y.X.; Marks, T. J.Chem. Rev.2000,100, 1391.

2. Modeling Metal-Catalyzed Olefin Polymerization

3. A density functional study on the formation of stereoerrors in the stereoselective propene polymerization with zirconocene catalysts

4. A Density Functional Study of Ion-Pair Formation and Dissociation in the Reaction between Boron- and Aluminum-Based Lewis Acids with (1,2-Me2Cp)2ZrMe2

5. A Combined Density Functional and Molecular Dynamics Study on Ethylene Insertion into the Cp2ZrEt−MeB(C6F5)3 Ion-Pair

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