Chelation Effect in Polymerization of Cyclic Esters by Metal Alkoxides: Structure Characterization of the Intermediate Formed by Primary Insertion of Lactide into the Al−OR Bond of an Organometallic Initiator
Author:
Affiliation:
1. Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664, Warsaw, Poland, and Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om050295v
Reference25 articles.
1. Remarkable Stereocontrol in the Polymerization of Racemic Lactide Using Aluminum Initiators Supported by Tetradentate Aminophenoxide Ligands
2. Towards the Nature of Active Sites in Polymerization of Cyclic Esters Initiated by Aluminium Alkoxides: First Structurally Authenticated Aluminium-?-Caprolactone Complex
3. Macromolecular engineering of polylactones and polylactides. 5. Synthesis and characterization of diblock copolymers based on poly-iε-caprolactone and poly(L,L or D,L)lactide by aluminum alkoxides
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