Isopentenyl Diphosphate Isomerase Catalyzed Reactions in D2O: Product Release Limits the Rate of This Sluggish Enzyme-Catalyzed Reaction
Author:
Affiliation:
1. Department of Chemistry, University at Buffalo, Buffalo, New York 14260, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja302154k
Reference23 articles.
1. ISOPENTENOL PYROPHOSPHATE ISOMERASE
2. Mechanism of action of isopentenyl pyrophosphate isomerase: evidence for a carbonium ion intermediate
3. Isopentenyl-diphosphate isomerase: inactivation of the enzyme with active-site-directed irreversible inhibitors and transition state analogs
4. Diversity of the biosynthesis of the isoprene units
5. Mechanism for Nucleophilic Substitution and Elimination Reactions at Tertiary Carbon in Largely Aqueous Solutions: Lifetime of a Simple Tertiary Carbocation
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