Silicon−Carbon Unsaturated Compounds. 57. Photolysis of meso- and racemic-1,2-Diethyl-1,2-dimethyldiphenyldisilane, Direct Evidence for a Concerted 1,3-Silyl Shift to ortho-Carbon in the Phenyl Ring
Author:
Affiliation:
1. Contribution from the Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima 724, Japan, and Department of Molecular Engineering, Faculty of Engineering, Kyoto University, Kyoto 606-01, Japan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja960458u
Reference23 articles.
1. Photolysis of organopolysilanes. Novel addition reaction of aryl substituted disilanes to olefins
2. Photochemically generated silicon—carbon double-bonded intermediates
3. Photochemistry of Organopolysilanes
4. Photochemistry of 1,2-di-tert-butyl-1,1,2,2-tetraphenyldisilane, a clean, direct source of arylalkylsilyl radicals
5. Reactive intermediates from the photolysis of methylpentaphenyl- and pentamethylphenyldisilane
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