The Magnesium−Ene Cyclization Stereochemically Directed by an Allylic Oxyanionic Group and Its Application to a Highly Stereoselective Synthesis of (±)-Matatabiether. Allylmagnesium Compounds by Reductive Magnesiation of Allyl Phenyl Sulfides1

Author:

Cheng Dai1,Zhu Shirong1,Yu Zhifang1,Cohen Theodore1

Affiliation:

1. Contribution from the Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference25 articles.

1. Reviews:  Klumpp, G. W.Recl. Trav. Chim. Pays-Bas1986,105, 1−20. Vara Prasad, J. V. N.; Pillai, C. N.Organometallics1983, 259, 1−30. Marek, I.; Normant, J.F. InMetal Catalyzed Cross Coupling Reactions;Diederich, F., Stang, P., Eds.; Wiley VCH:  New York, 1998; pp 269−335.

2. (a) Reviews of metallo−ene reactions:  Oppolzer, W.Angew. Chem.Int. Ed. Engl.1989,28, 38−52. Oppolzer, W. InComprehensive OrganicSynthesis; Trost, B. M., Ed.; Pergamon Press:  Oxford, England, 1991; Vol. 5, pp 29−61.

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