Nonclassical Bonding in Titanasilacyclohexadiene Compounds Resulting from Highly Methyl-Substituted Titanocene−Bis(trimethylsilyl)ethyne Complexes and Bis((trimethylsilyl)ethynyl)silanes

Author:

Horáček Michal1,Štěpnička Petr1,Gyepes Róbert1,Císařová Ivana1,Kubišta Jiří1,Lukešová Lenka1,Meunier Philippe1,Mach Karel1

Affiliation:

1. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23 Prague 8, Czech Republic, Department of Inorganic Chemistry, Faculty of Science, Charles University, Prague, Czech Republic, and Laboratoire de Synthèse et d'Electrosynthèse Organométalliques associé au CNRS (LSEO UMR 5632), Université de Bourgogne, Faculté des Sciences Gabriel, Dijon, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference45 articles.

1. (a) Rosenthal, U.; Burlakov, V. V. InTitanium and Zirconium inOrganic Synthesis; Marek, I., Ed.; Wiley-VCH:  Weinheim, Germany, 2002; p 355.

2. The Titanocene Complex of Bis(trimethylsilyl)acetylene:  Synthesis, Structure, and Chemistry

3. What Do Titano- and Zirconocenes Do with Diynes and Polyynes?

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