The Effect of Solvent on the Structure of the Transition State for the SN2 Reaction between Cyanide Ion and Ethyl Chloride in DMSO and THF Probed with Six Different Kinetic Isotope Effects-Reference-Cited by-同舟云学术

The Effect of Solvent on the Structure of the Transition State for the SN2 Reaction between Cyanide Ion and Ethyl Chloride in DMSO and THF Probed with Six Different Kinetic Isotope Effects

Published:2006-05-19 Issue:13 Volume:71 Page:4742-4747
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Fang Yao-ren¹,MacMillar Susanna¹,Eriksson Jonas¹,Kołodziejska-Huben Magdalena¹,Dybała-Defratyka Agnieszka¹,Paneth Piotr¹,Matsson Olle¹,Westaway Kenneth Charles¹

Affiliation:

1. Department of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario, P3E 2C6, Canada, Division of Organic Chemistry, Department of Chemistry, Uppsala University, P.O. Box 576, SE-75123, Uppsala, Sweden, and Institute of Applied Radiation Chemistry, Technical University of £odz, Zeromskiego 116, 90-924, Łodz, Poland

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo052375e

Reference30 articles.

1. Solvent effects on the structure of SN2 transition states

2. Experimental and Theoretical Multiple Kinetic Isotope Effects for an SN2 Reaction. An Attempt to Determine Transition-State Structure and the Ability of Theoretical Methods to Predict Experimental Kinetic Isotope Effects

3. Gordon, A. J.; Ford, R. A. InThe Chemist's Companion; John Wiley & Sons: New York, 1972; pp 6 and 7.

4. Thermochemistry and structures of solvated SN2 complexes and transition states in the gas phase: experiment and theory

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