Total Synthesis of (−)-Herbindoles A, B, and C via Transition-Metal-Catalyzed Intramolecular [2 + 2 + 2] Cyclization between Ynamide and Diynes
Author:
Affiliation:
1. Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol300571b
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2. Total syntheses of trikentrins and of herbindoles
3. Total synthesis of (+)-Herbindole A, (+)-herbindole B, and (+)-herbindole C. Determination of the absolute configuration of the natural herbindoles
4. Preparation of Alkyl-Substituted Indoles in the Benzene Portion. Part 11. Total Synthesis of (6R,8S)-Herbindole A, (6R,8S)-Herbindole B, (6R,8S)-Herbindole C, (6R,8S)-cis-Trikentrin A, (6R,8S)-cis-Trikentrin B, (6R,8R)-trans-Trikentrin B, and (6R,8R)-iso-trans-Trikentrin B. Determination of the Absolute Structures of Natural Herbindoles and Trikentrins.
5. Total Synthesis of (±)-Herbindole B and (±)-cis-Trikentrin B
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