Unexpected catalysis: aprotic pyridinium ions as active and recyclable Brønsted acid catalysts in protic media
Author:
Affiliation:
1. Centre for Synthesis and Chemical Biology, School of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol802008m
Reference27 articles.
1. A reductase-mimicking thiourea organocatalyst incorporating a covalently bound NADH analogue: efficient 1,2-diketone reduction with in situ prosthetic group generation and recycling
2. Catalytic Hydrogenation of α,β-Epoxy Ketones to Form β-Hydroxy Ketones Mediated by an NADH Coenzyme Model
3. Catalysts/ionic liquids which incorporateN-alkylpyridinium ions for which no specific catalytic role has been identified for the pyridinium ring other than as a polar/or electron-deficient group have been reported; for representative recent examples, see:
4. N-Alkyl-4-boronopyridinium Salts as Thermally Stable and Reusable Amide Condensation Catalysts
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