Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical. The Role of Hydrogen Bonding
Author:
Affiliation:
1. Dipartimento di Scienze e Tecnologie Chimiche, Università “Tor Vergata”, Via della Ricerca Scientifica, 1 I-00133 Rome, Italy
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol101448e
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1. Radical Scavenging Reactivity of Catecholamine Neurotransmitters and the Inhibition Effect for DNA Cleavage
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4. Switch-Over in Photochemical Reaction Mechanism from Hydrogen Abstraction to Exciplex-Induced Quenching: Interaction of Triplet-Excited versus Singlet-Excited Acetone versus Cumyloxyl Radicals with Amines
5. Chemistry of the t-Butoxyl Radical: Evidence that Most Hydrogen Abstractions from Carbon are Entropy-Controlled
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