Role of the Metal Oxidation State in the SNS−Cr Catalyst for Ethylene Trimerization: Isolation of Di- and Trivalent Cationic Intermediates
Author:
Affiliation:
1. Contribution from the Department of Chemistry, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada, and Department of Chemistry, Eindhoven University of Technology, P.O.Box 513, 5600 MB, The Netherlands
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja0623717
Reference54 articles.
1. Advances in selective ethylene trimerisation – a critical overview
2. Hemilabile Ligand Induced Selectivity: a DFT Study on Ethylene Trimerization Catalyzed by Titanium Complexes
3. Catalytic Oligomerization of Ethylene to Higher Linear α-Olefins Promoted by Cationic Group 4 Cyclopentadienyl-Arene Active Catalysts: Toward the Computational Design of Zirconium- and Hafnium-Based Ethylene Trimerization Catalysts
4. Mechanism of Ethene Trimerization at an ansa-(Arene)(cyclopentadienyl) Titanium Fragment
5. A DFT Study toward the Mechanism of Chromium-Catalyzed Ethylene Trimerization
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