Synthetic and Mechanistic Investigations of Trimethylsilyl-Substituted Triamidoamine Complexes of Tantalum That Contain Metal−Ligand Multiple Bonds
Author:
Affiliation:
1. Contribution from the Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja953826n
Reference57 articles.
1. Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N]
2. Trigonal-Monopyramidal MIII Complexes of the Type[M(N3N)](M= Ti, V, Cr, Mn, Fe; N3N=[(tBuMe2Si)CH2CH2]3N)
3. Phosphinidenetantalum(V) Complexes of the Type[(N3N)TaPR] as Phospha-Wittig Reagents
4. Synthesis of Molybdenum and Tungsten Complexes That Contain Triamidoamine Ligands of the Type (C6F5NCH2CH2)3N and Activation of Dinitrogen by Molybdenum
5. Organometallic Complexes of Tantalum That Contain the Triamidoamine Ligand, [(Me3SiNCH2CH2)3N]3-, Including an Ethylidene Complex Formed via a Phosphine-Catalyzed Rearrangement of an Ethylene Complex
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