Experimental and Theoretical Studies on the Nucleofugality Patterns in the Aminolysis and Phenolysis of S-Aryl O-Aryl Thiocarbonates-Reference-Cited by-同舟云学术

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Experimental and Theoretical Studies on the Nucleofugality Patterns in the Aminolysis and Phenolysis of S-Aryl O-Aryl Thiocarbonates

Published:2009-11-12 Issue:23 Volume:74 Page:9173-9179
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Castro Enrique A.¹,Aliaga Margarita¹,Campodónico Paola R.²,Cepeda Marjorie¹,Contreras Renato³,Santos José G.¹

Affiliation:

1. Facultad de Química, Pontificia Universidad Católica de Chile, Casilla 306, Santiago 6094411, Chile

2. Instituto de Ciencias, Facultad de Medicina, Clínica Alemana Universidad del Desarrollo, Santiago 7710162, Chile

3. Departamento de Química, Facultad de Ciencias, Universidad de Chile, Casilla 653, Santiago, Chile

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo902005y

Reference35 articles.

1. Kinetics and Mechanisms of Reactions of Thiol, Thiono, and Dithio Analogues of Carboxylic Esters with Nucleophiles

2. Kinetics and mechanisms of reactions of thiol, thiono and dithio analogues of carboxylic esters with nucleophiles. An update

3. Aminolysis and pyridinolysis ofO-arylS-(4-nitrophenyl) thiocarbonates in aqueous ethanol. Kinetics and mechanism

4. Group electrophilicity as a model of nucleofugality in nucleophilic substitution reactions

5. Kinetics and mechanism of the aminolysis of 2,4-dinitrophenyl and 2,4,6-trinitrophenyl thiolacetates

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1. Reactions of 2,4‐dinitrophenyl 5‐substituted‐2‐thiophenecarboxylate promoted by 4‐ZC₆H₄O⁻/4‐ZC₆H₄OH in 20 mol% DMSO(aq). Effects of leaving group and nucleophile on the acyl transfer reactions;Bulletin of the Korean Chemical Society;2023-09

2. Reactions of 4‐Nitrophenyl 5‐substituted Furan‐2‐carboxylates with R 2 NH / R 2 NH 2 + in 20 mol% DMSO (aq): Effect of Aryl Group on the Acyl‐Transfer Reaction;Bulletin of the Korean Chemical Society;2021-05-09

3. The effect of the electrophilic group on the hierarchy of nucleofuges in the aminolysis reactions of thiol- and dithiocarbonates with secondary alicyclic amines: A kinetic and theoretical study;New Journal of Chemistry;2019

4. Theoretical insights into the E1cB/E2 mechanistic dichotomy of elimination reactions;Organic & Biomolecular Chemistry;2019

5. Activation of Electrophile/Nucleophile Pair by a Nucleophilic and Electrophilic Solvation in a SNAr Reaction;Frontiers in Chemistry;2018-10-23

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