An Unprecedented High-Nuclearity Closest-Packed Bimetallic Palladium Carbonyl Cluster: [Pd33Ni9(CO)41(PPh3)6]4- Containing a Pseudo-D3h hcp Pd33Ni9 Core-Reference-Cited by-同舟云学术

An Unprecedented High-Nuclearity Closest-Packed Bimetallic Palladium Carbonyl Cluster: [Pd33Ni9(CO)41(PPh3)6]4- Containing a Pseudo-D3h hcp Pd33Ni9 Core

Published:1996-01-01 Issue:33 Volume:118 Page:7869-7870
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Kawano Masaki¹,Bacon Jeffrey W.¹,Campana Charles F.¹,Dahl Lawrence F.¹

Affiliation:

1. Department of Chemistry University of WisconsinMadison Madison, Wisconsin 53706 Siemens Analytical X-Ray Instruments 6300 Enterprise Lane, Madison, Wisconsin 53719

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja960681r

Reference55 articles.

1. Synthesis and structural characterization of the [Ni9(AsPh)3(CO)15]2- and [Ni10(AsMe)2(CO)18]2- dianions containing noncentered icosahedral Ni12-xAsx cores (x = 2, 3): electronically equivalent metal cluster analogs of the regular icosahedral [B12H12]2- dianion

2. Reactions of the [Ni6(CO)12]2- dianion with stibine and bismuthine reagents: synthesis and stereophysical characterization of the [Ni10(SbPh)2(CO)18]2- dianion containing a noncentered icosahedral Ni10Sb2 core and Ni2(CO)4(μ2-Ph2SbOSbPh2)2 containing a centrosymmetric eight-membered (NiSbOSb)2 ring

3. Synthesis, chromatographic separation, and stereophysical analysis of the homologous [Ni12-x(PMe)x(CO)24-3x]2- series (x = 2, 3, 4) containing noncentered Ni12-xPx icosahedral cages and the [Ni10(.mu.5-PMe)2(.mu.4-PMe)5(CO)10]2- dianion containing a structurally unprecedented heptacapped pentagonal prismatic metal cage: structural, spectroscopic, and electrochemical consequences due to replacement of Ni(CO)3 fragments with electronically equivalent (isolobal) PMe fragments

4. A new family of icosahedral cages with transition metal and main group IV (14) atoms: synthesis and structural-bonding analysis of the [Ni11(SnR)2(CO)18]2- dianions (R = Bu, Me) containing nickel-centered icosahedral Ni10Sn2 cages and of their unusual [Ni(SnRCl2)4(CO)]2- precursors containing a trigonal-bipyramidal d8 nickel(II) configuration

5. A new family of 14-vertex hexacapped metal cubes with main group IV (14) atoms: synthesis and structural-bonding analysis of Ni9(.mu.4-GeEt)6(CO)8 containing a nickel-centered Ni8(.mu.4-Ge)6 cubic cage with an unusual electron count

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