Electron Distribution, Bonding, and J(Si−H) NMR Coupling Constant in (η5-C5H5)(CO)2MnHSiCl3: The Molecular Orbital View
Author:
Affiliation:
1. Center for Gas-Phase Electron Spectroscopy, Department of Chemistry, The University of Arizona, Tucson, Arizona 85721
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om030121i
Reference31 articles.
1. η2 Coordination of Si–H σ Bonds to Transition Metals
2. Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds
3. Electronic structure factors of silicon-hydrogen bond activation by transition metals. The valence photoelectron spectrum of silylmanganese complex (.eta.5-C5H5)Mn(CO)2HSiCl3
4. Electronic structure control of silicon-hydrogen bond activation by transition metals. 2. Valence photoelectron spectra of (.eta.5-C5H4CH3)Mn(CO)2HSiPh3, (.eta.5-C5H4CH3)Mn(CO)2HSiHPh2 and (.eta.5-C5H4CH3)Mn(CO)2HSiFPh2 (Ph = C6H5)
5. Electronic structure factors of silicon-hydrogen bond activation by transition metals. Valence photoelectron spectra of (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiCl3 and (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiHPh2 (Me = CH3, Ph = C6H5)
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