Nucleophilic Addition Reactions of the Osmium−Antimony Cluster (μ-H)Os3(CO)9(μ3-C6H4)(μ-SbPh2): Orthometalation of Triphenylphosphine at Ambient Temperature
Author:
Affiliation:
1. Department of Chemistry, National University of Singapore, Kent Ridge, Singapore 119260
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om010959a
Reference33 articles.
1. Intermediates in the conversion of [Os3(CO)11(PRPh2)](R = Me or Ph) into [Os3(µ3-C6H4)(µ3–PR)(CO)9]: crystal and molecular structures of [Os3-(µ-H)(µ3-C6H4PMePh-o)(CO)9] and [Os3(µ3-C6H4PMe-o)(CO)10]
2. New mode of ‘benzyne’ co-ordination. Crystal and molecular structure of Os3(CO)9(PEt)(C6H4)
3. Mode of attachment of the triply-bridging C6H4 ligand in open triosmium clusters: Crystal structures and fluxionality of the clusters [Os3(PMe)(C6H4)(CO)8L] (L = CO or PEt3)
4. Preparation and structure of Ru3(CO)7(.mu.3-.eta.2-C6H4)(.mu.-PPhFc)2
5. (Benzyne)chromium tricarbonyl. Preparation and structure of Ru3(CO)9{.mu.3-P[C6H5Cr(CO)3]}[.mu.3-C6H4Cr(CO)3] and Ru3(CO)7(.mu.3-C6H4){.mu.-PPh[C6H5Cr(CO)3]}2
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1. Polynuclear ruthenium clusters containing stibine, stibene, and stibinidene ligands;Journal of Organometallic Chemistry;2023-01
2. Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage;RSC Advances;2023
3. Reaction of the Decaosmium Carbido Cluster [Os10(µ6-C)(CO)24]2− with Halostibines;Journal of Cluster Science;2020-08-09
4. Synthesis and structure of open and closed type iron telluride – stibine cluster compounds;Journal of Organometallic Chemistry;2017-11
5. Ligand substitution in the osmium-antimony rings Os3(μ-SbPh2)2 (CO)10 and Os3(μ-SbPh2)3(Cl)(CO)9;Journal of Organometallic Chemistry;2016-10
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