Metal−Metal Cooperativity Effects in Promoting C−H Bond Cleavage of a Methyl Group by an Adjacent Metal Center
Author:
Affiliation:
1. Contribution from the Department of Chemistry, University of Alberta, Edmonton, AB, Canada T6G 2G2, and Department of Chemistry and Biochemistry, Calvin College, Grand Rapids, Michigan 49546-4388
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja983525o
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4. Crabtree, R. H.The Organometallic Chemistry of the Transition Metals; John Wiley & Sons: New York, 1988; p 327.
5. Activation of hydrocarbons by unsaturated metal cluster complexes. 6. Synthesis and characterization of methyldecacarbonylhydridotriosmium, methylenedecacarbonyldihydridotriosmium, and methylidynenonacarbonyltrihydridotriosmium. Interconversion of cluster-bound methyl and methylene ligands
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