Metal−Metal Cooperativity Effects in Promoting C−H Bond Cleavage of a Methyl Group by an Adjacent Metal Center

Author:

Torkelson Jeffrey R.1,Antwi-Nsiah Frederick H.1,McDonald Robert1,Cowie Martin1,Pruis Justin G.1,Jalkanen Karl J.1,DeKock Roger L.1

Affiliation:

1. Contribution from the Department of Chemistry, University of Alberta, Edmonton, AB, Canada T6G 2G2, and Department of Chemistry and Biochemistry, Calvin College, Grand Rapids, Michigan 49546-4388

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference73 articles.

1. The organometallic chemistry of metal surfaces

2. Surface-bound metal hydrocarbyls. Organometallic connections between heterogeneous and homogeneous catalysis

3. Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G.Principles andApplications of Organotransition Metal Chemistry; University Science Books:  Mill Valley, CA, 1987; p 383.

4. Crabtree, R. H.The Organometallic Chemistry of the Transition Metals; John Wiley & Sons:  New York, 1988; p 327.

5. Activation of hydrocarbons by unsaturated metal cluster complexes. 6. Synthesis and characterization of methyldecacarbonylhydridotriosmium, methylenedecacarbonyldihydridotriosmium, and methylidynenonacarbonyltrihydridotriosmium. Interconversion of cluster-bound methyl and methylene ligands

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