Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters
Author:
Affiliation:
1. Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9026852
Reference25 articles.
1. Highly Enantio- and Diastereoselective Construction of 1,2-Disubstituted Cyclopentane Compounds by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]-Catalyzed CH Insertion Reactions of α-Diazo Esters
2. Dirhodium(II) tetrakis[N-tetrafluorophthaloyl-(S)-tert-leucinate]: an exceptionally effective Rh(II) catalyst for enantiotopically selective aromatic C–H insertions of diazo ketoesters
3. Enantio- and Diastereoselective Synthesis of cis-2-Aryl-3-methoxycarbonyl-2,3-dihydrobenzofurans via the Rh(II)-Catalyzed C−H Insertion Process
4. Catalytic Enantioselective Intermolecular Cycloaddition of 2-Diazo-3,6-diketoester-Derived Carbonyl Ylides with Alkynes and Styrenes Using Chiral Dirhodium(II) Carboxylates
5. Catalytic Enantioselective Tandem Carbonyl Ylide Formation/1,3-Dipolar Cycloaddition Reactions of α-Diazo Ketones with Aromatic Aldehydes using Dirhodium(II) Tetrakis[N-benzene-fused-phthaloyl-(S)-valinate]
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1. A Desymmetric Dearomatization Cyclopropanation of [2.2]Paracyclophane;CCS Chemistry;2024-08-05
2. Rh-Catalyzed Enantioselective Single-Carbon Insertion of Alkenes;Journal of the American Chemical Society;2024-07-26
3. Synthesis of fluorine-containing α-alkyl-α-diazoesters and their utility in enantioselective cyclopropanation;Tetrahedron Letters;2024-06
4. Origin of the Conformational Stability of Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate] and Its Halogenated Derivatives;The Journal of Physical Chemistry A;2024-04-16
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