Kinetics and Mechanism of the Pyridinolysis of O-Ethyl S-Aryl Thiocarbonates in Aqueous Solution
Author:
Affiliation:
1. Facultad de Quimica, Pontificia Universidad Católica de Chile, Casilla 306, Santiago 22, Chile
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo960781f
Reference31 articles.
1. Mechanism of the aminolysis of acetate esters
2. Ester aminolysis. Structure-reactivity relationships and the rate-determining step in the aminolysis of substituted diphenyl carbonates
3. Kinetics of reaction of p-nitrophenyl methyl carbonate with nucleophiles in aqueous solution, and the relative ease of acetyl and methoxycarbonyl transfer reactions
4. Curved Broensted plot in pyridinolysis of 2,4-dinitrophenyl methyl carbonate. Comparison of leaving group abilities between pyridines and phenolates
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