Mechanistic and Computational Study of a Palladacycle-Catalyzed Decomposition of a Series of Neutral Phosphorothioate Triesters in Methanol
Author:
Affiliation:
1. Department of Chemistry, Queen’s University, Kingston, Ontario, Canada K7L 3N6
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja107144c
Reference76 articles.
1. aToy, A. D. F. and Walsh, E. N.InPhosphorus Chemistry in Everyday Living,2nded.American Chemical Society:Washington, DC, 1987; pp18−20.
2. bQuin, L. D.InA Guide to Organophosphorus Chemistry;Wiley:New York; 2000; pp367−371.
3. Billion-fold Acceleration of the Methanolysis of Paraoxon Promoted by La(OTf)3 in Methanol
4. La3+-catalyzed methanolysis of O,O-diethyl S-(p-nitrophenyl) phosphorothioate and O,O-diethyl S-phenyl phosphorothioate. Millions-fold acceleration of the destruction of V-agent simulants
5. Zn2+-Catalyzed Methanolysis of Phosphate Triesters: A Process for Catalytic Degradation of the Organophosphorus Pesticides Paraoxon and Fenitrothion
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