Preferred Coordination Sites for Metal Fragments in σ,π-Bimetallic Complexes. Detailed Mechanistic Insight from Heteroatom, Bridging Ligand, Solvent, Temperature, and Pressure Effects on the Irreversible Exchange of Coordination Sites1-Reference-Cited by-同舟云学术

Preferred Coordination Sites for Metal Fragments in σ,π-Bimetallic Complexes. Detailed Mechanistic Insight from Heteroatom, Bridging Ligand, Solvent, Temperature, and Pressure Effects on the Irreversible Exchange of Coordination Sites1

Published:1997-09-01 Issue:19 Volume:16 Page:4056-4070
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Waldbach Thomas A.¹,van Eldik Rudi¹,van Rooyen Petrus H.¹,Lotz Simon¹

Affiliation:

1. Department of Chemistry, University of Pretoria, Pretoria 0002, South Africa, and Institute for Inorganic Chemistry, University of Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om970494h

Reference88 articles.

1. Trimetallic complexes with .sigma.,.sigma.,.pi.-bonded thienylene ligands

2. Methods for the Synthesis of ?-Hydrocarbon Transition Metal Complexes without Metal-Metal Bonds

3. .pi.-Arene complexes. 7. Heterobimetallic complexes of chromium and manganese with bridging .sigma.,.pi.-benezene and -benzoyl ligands

4. .pi.-Arene complexes. 8. Early/late heterobimetallic complexes in chromium with .sigma.,.pi.-bridged arene ligands

5. π-Arene complexes IX. Crystal structure of a novel benzoyl bridged heterobimetallic complex, [cis-(CO)4{(MeO)3P}Mn{μ-η1:η6-C6H5C(O)}Cr(CO)3]

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