Stereoselective Generation of E- and Z-Disubstituted Amide Enolates. Reductive Enolate Formation from Bicyclic Thioglycolate Lactams
Author:
Affiliation:
1. Department of Chemistry, McGill University 801 Sherbrooke St. West, Montreal, QC, Canada H3A 2K6
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja0058280
Reference14 articles.
1. The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation
2. Role of HMPT and TMEDA in control of enolate stereochemistry for reactions of lithium amides with 3-pentanone
3. Highly selective, kinetically controlled enolate formation using lithium dialkylamides in the presence of trimethylchlorosilane
4. Stereochemical control in the ester enolate Claisen rearrangement. 1. Stereoselectivity in silyl ketene acetal formation
5. Enantioselective alkylation of chiral enolates
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