Dynamic Kinetic Asymmetric Ring-Opening/Reductive Amination Sequence of Racemic Nitroepoxides with Chiral Amines: Enantioselective Synthesis of Chiral Vicinal Diamines
Author:
Affiliation:
1. Departament de Química Inorgànica i Orgànica, Universitat Jaume I, 12080 Castelló, Spain
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo400501k
Reference25 articles.
1. De-racemization of Enantiomers versus De-epimerization of Diastereomers-Classification of Dynamic Kinetic Asymmetric Transformations (DYKAT)
2. For more interesting examples on dynamic resolutions see:Wolf, C.InDynamic Stereochemistry of Chiral Compounds;RSC-Publishing:Cambridge, U.K., 2008; pp372–377.
3. Rhodium(II)-Catalyzed Enantioselective C−H Functionalization of Indoles
4. Catalytic Dynamic Kinetic Resolutions with N-Heterocyclic Carbenes: Asymmetric Synthesis of Highly Substituted β-Lactones
5. Amidines, isothioureas, and guanidines as nucleophilic catalysts
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