Kinetics of the Deprotonation of Methylnitroacetate by Amines: Unusually High Intrinsic Rate Constants for a Nitroalkane
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo070372r
Reference59 articles.
1. Thermodynamic and kinetic acidity properties of nitroalkanes. Correlation of the effects of structure on the ionization constants and the rate constants of neutralization of substituted 1-phenyl-1-nitroethanes
2. Acidities, Broensted coefficients, and transition state structures for 1-arylnitroalkanes
3. Kinetic and equilibrium acidities for nitroalkanes
4. The Nitroalkane Anomaly
5. Rates and kinetic hydrogen isotope effects for the ionization of phenylnitromethane
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