Nickel Ethylene Polymerization Catalysts Based on Phosphorus Ligands

Author:

Cooley Neil A.,Green Simon M.,Wass Duncan F.,Heslop Katie,Orpen A. Guy,Pringle Paul G.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference15 articles.

1. New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

2. Synthesis of Branched Polyethylene Using (α-Diimine)nickel(II) Catalysts:  Influence of Temperature, Ethylene Pressure, and Ligand Structure on Polymer Properties

3. (c) Johnson, J. K.; Killian, C. M.; Arthur, S. D.; Feldman, J.; McCord, E. F.; McLain, S. J.; Kreutzer, K. A.; Bennett, A. M. A.; Coughlin, E. B.; Ittel, S. D.; Parthasarathy, A.; Tempel, D. J.; Brookhart, M. WO 96/23010 (to DuPont)1996[Chem. Abstr.1996,125, 222773t].

4. We have recently reported the activity of these ligands in palladium-catalyzed ethylene/CO copolymerization:  (a) Dossett, S. J. WO 97/37765 (to BP Chemicals). (b) Dossett, S. J. WO 00/06299 (to BP Chemicals). (c) Dossett, S. J.; Gillon, A.; Orpen, A. G.; Fleming, J. S.; Pringle, P. G.; Wass, D. F.; Jones, M. D.Chem. Commun.2001, 699.

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