Photoionization via Absorption/Electron Transfer/Absorption Studied by Two-Pulse Two-Color Laser Flash Photolysis-Reference-Cited by-同舟云学术

Photoionization via Absorption/Electron Transfer/Absorption Studied by Two-Pulse Two-Color Laser Flash Photolysis

Published:1998-05-19 Issue:21 Volume:120 Page:5347-5348
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Goez Martin¹,Zubarev Valentin¹,Eckert Gerd¹

Affiliation:

1. Fachbereich Chemie, Martin−Luther-Universität Halle−Wittenberg, Kurt−Mothes-Strasse 2 D-06120 Halle/Saale, FRG

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja980040r

Reference10 articles.

1. Absorption/Elektronentransfer/Absorption – ein effizienter Weg zu hydratisierten Elektronen bei der Laserblitzlichtphotolyse

2. Sulfuranes. XVIII. Stereochemical course of an associative nucleophilic displacement at tetracoordinate sulfur(IV). Optically active trigonal bipyramidal molecule, a chlorosulfurane

3. Fits of the experimental traces to the pertaining reaction scheme gave rate constants of 3.3 × 105s-1and 3.4 × 109M-1s-1for the transformation TEA•+→ TEA•and the reduction of CB by TEA•, respectively. As the final absorbance of CB•-is noticeably smaller than twice the value of the absorbance immediately after quenching of3CB, additional decay channels of TEA•+or TEA•or both must exist, which are contained in these apparent rate constants.

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