Allylic Substitution on Cyclopentene and -hexene Rings with Alkynylcopper Reagents
Author:
Affiliation:
1. Department of Biomolecular Engineering, Tokyo Institute of Technology Box B52, Nagatsuta-cho 4259, Midori-ku, Yokohama 226-8501, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol202711k
Reference29 articles.
1. Formation of Chiral C(sp3)−C(sp) Bond by Allylic Substitution of Secondary Allylic Picolinates and Alkynyl Copper Reagents
2. Picolinoxy Group, a New Leaving Group for anti SN2′ Selective Allylic Substitution with Aryl Anions Based on Grignard Reagents
3. New General Method for Regio- and Stereoselective Allylic Substitution with Aryl and Alkenyl Coppers Derived from Grignard Reagents
4. Highly efficient substitution of allylic picolinates with copper reagents derived from aryl-, alkenyl-, furyl-, and thienyl-lithiums
5. Construction of a quaternary carbon at the carbonyl carbon of the cyclohexane ring
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