A Simple Electrostatic Model for Trisilylamine: Theoretical Examinations of the n→σ* Negative Hyperconjugation, pπ→dπ Bonding, and Stereoelectronic Interaction-Reference-Cited by-同舟云学术

A Simple Electrostatic Model for Trisilylamine: Theoretical Examinations of the n→σ* Negative Hyperconjugation, pπ→dπ Bonding, and Stereoelectronic Interaction

Published:1999-06-01 Issue:24 Volume:121 Page:5737-5742
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Mo Yirong¹,Zhang Yongqing¹,Gao Jiali¹

Affiliation:

1. Contribution from the Department of Chemistry and State Key Laboratory for Physical Chemistry on Solid Surface, Xiamen University, Xiamen 361005, People's Republic of China, and Department of Chemistry and Center for Computational Research, State University of New York at Buffalo, Buffalo, New York 14260

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja9904742

Reference50 articles.

1. The Chemistry of Silicon-Nitrogen Compounds.

2. Quantum chemical calculations of the structure of N-silylaniline derivatives

3. Gas phase basicity of silanamines

4. Photoelectron spectroscopic and theoretical study of tris(trimethylsilyl)amine and related silylamines. Real and hypothetical planar tertiary amines

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