Scalable Synthesis of Enantiomerically Pure Bicyclo[2.2.2]octadiene Ligands
Author:
Affiliation:
1. Process Research Chemistry, Actelion Pharmaceuticals Ltd., Gewerbestrasse 16, CH-4123 Allschwil, Switzerland
2. Chemical Development and Catalysis, Solvias AG, Römerpark 2, CH-4303 Kaiseraugst, Switzerland
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo3005638
Reference45 articles.
1. A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts: Its Preparation and Use for the Rhodium-Catalyzed Asymmetric 1,4-Addition
2. Readily Available [2.2.2]-Bicyclooctadienes as New Chiral Ligands for Ir(I): Catalytic, Kinetic Resolution of Allyl Carbonates
3. Chiral Olefin Ligands—New“Spectators” in Asymmetric Catalysis
4. Chiral Olefins as Steering Ligands in Asymmetric Catalysis
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