Nickel-Catalyzed, Carbonyl-Ene-Type Reactions:  Selective for Alpha Olefins and More Efficient with Electron-Rich Aldehydes

Author:

Ho Chun-Yu1,Ng Sze-Sze1,Jamison Timothy F.1

Affiliation:

1. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference17 articles.

1. Reviews:  (a) Hoffmann, H. M. R.Angew. Chem., Int. Ed. Engl.1969,8, 556−577. (b) Snider, B. B.Acc. Chem. Res.1980,13, 426−432. (c) Snider, B. InComprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press:  Oxford, 1991; Vol. 2, pp 527−561. (d) Mikami, K.; Shimizu, M.Chem. Rev.1992,92, 1021−1050. (e) Dias, L. C.Curr. Org.Chem.2000,4, 305−342.

2. Coenzyme models. 31. Efficient trapping of transient thiazolium-aldehyde adducts (active aldehydes) by intramolecular and quasi-intramolecular flavins. Flavin-thiamin biscoenzyme

3. Reactions of β-Pinene with Aromatic Aldehydes

4. Stereoselective construction of 22-oxygenated steroid side chains by dimethylaluminum chloride-mediated ene reactions of aldehydes

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