Enantioselective Synthesis of α-Stereogenic γ-Keto Esters via Formal Umpolung-Reference-Cited by-同舟云学术

Enantioselective Synthesis of α-Stereogenic γ-Keto Esters via Formal Umpolung

Published:2012-06-18 Issue:13 Volume:14 Page:3260-3263
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Prakash G. K. Surya¹,Wang Fang¹,Zhang Zhe¹,Ni Chuanfa¹,Haiges Ralf¹,Olah George A.¹

Affiliation:

1. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angeles, California 90089-1661, United States

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ol301112m

Reference74 articles.

1. .beta.-Keto sulfoxides. VII. Conversion into .gamma.- and .delta.-keto esters

2. Michael reaction of conjugated nitro olefins with carboxylic acid dianions and with ester enolates: new synthesis of .gamma.-keto acids and .gamma.-keto esters

3. The Michael reaction of silyl enol ethers or ketene silyl acetals with conjugated nitro olefins activated by Lewis acids: new synthesis of 1,4-diketones and .gamma.-oxo esters

4. A new tributyltin hydride-based rearrangement of bromomethyl .beta.-keto esters. A synthetically useful ring expansion to .gamma.-keto esters

5. Synthesis of 1,4-dicarbonyl compounds via the conjugate addition of a masked activated ester, ROCH(CN)2

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