A Novel Titanium Tetrahalide-Mediated Carbon−Carbon Bond-Forming Reaction: Regioselective Synthesis of Substituted (E,Z)-1,5-Dihalo-1,4-dienes
Author:
Affiliation:
1. Departments of Chemistry and Radiology, The University of Tennessee, Knoxville, Tennessee 37996-1600
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol026507r
Reference51 articles.
1. Organotitanium Reagents in Organic Synthesis
2. TiCl4−n-Bu4NI as a Reducing Reagent: Pinacol Coupling and Enolate Formation from α-Haloketones
3. Reductive coupling of aromatic aldehydes and imines by the low valent titanium species generated in the reaction of TiCl4 with Et3N
4. Alkylation of carbonyl compounds in the TiCl4-promoted reaction of trimethylsilyl enol ethers with epoxides
5. A highly dl-stereoselective pinacolization of aromatic aldehydes mediated by TiCl4–Zn
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