High-Yield Synthesis of PPh3-Ligated Decanuclear Tl–Pd Cluster, Pd9[Tl(acac)](CO)9(PPh3)6: Comparative Analysis of Tl(I)–Pd(0) Bonding Connectivities with Known Tl–Pd Clusters and Resulting Insight Concerning Their Dissimilar Dynamic Solution Behavior
Author:
Affiliation:
1. Department of Chemistry, University of Wisconsin−Madison, Madison, Wisconsin 53706, United States
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om201150x
Reference36 articles.
1. First high-nuclearity thallium–palladium carbonyl phosphine cluster, [Tl2Pd12(CO)9(PEt3)9]2+, and its initial mistaken identity as the unknown Au2Pd12analogue: structure-to-synthesis approach concerning its formation
2. Formation of thallium(i) sandwich M3TlM3clusters, [(μ6-Tl)M6(μ2-CO)6(PEt3)6]+(M = Pt, Pd), with two unconnected triangular M3(μ2-CO)3(PEt3)3units: implications of comparative analysis of isostructural 5d106s2Tl(i)–(M3)2sandwiches (M = Pt, Pd) with known 5d10Au(i)–(Pt3)2sandwich
3. The First Trimetallic Pd/Tl/Co Carbonyl Cluster, Trigonal [Pd9{?3-TlCo(CO)3L}(?2-CO)6(?3-CO)3L6]: Ligand-Stabilization of the Trigonal-Bipyramidal [TlCo(CO)3L] Entity
4. The Cambridge Crystallographic Data Centre:www.ccdc.cam.ac.uk.
5. Bond Activation, Substrate Addition and Catalysis by an Isolable Two-Coordinate Pd(0) Bis-Isocyanide Monomer
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1. Octahedral Hexapalladium Pseudo-Td Pd6(μ3-CO)4(PEt3)6 with 80 Electron-Deficient Cluster Valence Electrons (CVEs) and a Comparison with Octahedral Hexapalladium Pseudo-C2v Pd6(μ3-CO)4(PMe3)7 with 82 CVEs: Computational Analysis and Resulting Implications;Inorganic Chemistry;2022-12-16
2. Group 9 and 10 Carbonyl Clusters;Comprehensive Organometallic Chemistry IV;2022
3. Stabilization of thallium(I) Pd 9 TlPd 3 sandwich monocation with octahedral-based [Pd 9 (CO) 9 (PMe 3 ) 6 ] and [Pd 3 (CO) 3 (PMe 3 ) 3 ] entities versus unstable Pd 3 Tl(I)Pd 3 sandwich monocation with [Pd 3 (CO) 3 (PEt 3 ) 3 ] entities: Comparative computational implications;Journal of Organometallic Chemistry;2015-09
4. Boron, aluminium, gallium, indium and thallium;Annual Reports Section "A" (Inorganic Chemistry);2013
5. How innocent is thallium(i)? Corrected formulations of [Tl2Pd14(CO)9(PMe3)11][PF6]2 and [TlPd9(CO)9(PPh3)6][PF6] clusters previously reported as corresponding Au2Pd14 and AuPd9 clusters;Chemical Communications;2013
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