Regioselective Asymmetric α,α-Bisalkylation of Ketones via Complex-Induced Syn-Deprotonation of Chiral N-Amino Cyclic Carbamate Hydrazones
Author:
Affiliation:
1. Department of Chemistry, Duke University, Durham, North Carolina 27708, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja202267k
Reference33 articles.
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2. bEnders, D.InAsymmetric Synthesis,1st ed.Morrison, J. D., Ed.Academic Press:New York, 1984; Vol.3, pp275–339.
3. The SAMP-/RAMP-hydrazone methodology in asymmetric synthesis
4. Enantioselective alkylation of cyclohexanone via chiral lithio-chelated enamines
5. Asymmetric alkylation of acyclic ketones via chiral metallo enamines. Effect of kinetic vs. thermodynamic metalations.
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