Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones
Author:
Affiliation:
1. Instituto Universitario de Química Organometálica “Enrique Moles” (Unidad Asociada al CSIC), Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, 33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om7011997
Reference56 articles.
1. Pyridine-2,6-bis(oxazolines), Helpful Ligands for Asymmetric Catalysts
2. Novel Iridium Complexes Containing 2,6-Bis(oxazoline)pyridine Ligands: Synthesis and Reactivity of the Diolefin Iridium(I) Complex [Ir(η2-C2H4)2{κ3N,N,N-(S,S)-i-Pr-pybox}][PF6] ((S,S)-i-Pr-pybox = 2,6-Bis(4‘-(S)-isopropyloxazolin-2‘-yl)pyridine)
3. Novel Carbonyliridium and ‐rhodium Complexes Containing 2,6‐Bis[(4′ S )‐4′‐isopropyloxazolin‐2′‐yl]pyridine ( i Pr‐pybox) and 2,6‐Bis[(4′ R )‐4′‐phenyloxazolin‐2′‐yl]pyridine (Ph‐pybox) Ligands
4. Enantio- and Diastereoselective Reductive Aldol Reactions with Iridium-Pybox Catalysts
5. Utility of the Iridium Complex of the Pybox Ligand in Regio- and Enantioselective Allylic Substitution
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