Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic η3-Cyclohexenyl Complex [(η3-c-C6H9)Pd(TSL)]+

Author:

Butts Craig P.1,Filali Emane1,Lloyd-Jones Guy C.1,Norrby Per-Ola1,Sale David A.1,Schramm York1

Affiliation:

1. School of Chemistry, University of Bristol, Cantock’s Close, Bristol, BS8 1TS, U.K., and Department of Chemistry, University of Gothenburg, Kemigården 4, SE-412 96 Göteborg, Sweden

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference111 articles.

1. Asymmetric Ligands for Transition-Metal-Catalyzed Reactions: 2-Diphenylphosphinobenzoyl Derivatives of C2-Symmetric Diols and Diamines

2. Recent reviews.

3. Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

4. bTrost, B. M. and Lee, C.Catalytic Asymmetric Synthesis,2nd ed;Ojima, I., Ed.Wiley-VCH:New York, 2000; pp593−649.

5. cPfaltz, A. and Lautens, M.Comprehensive Asymmetric Catalysis;Jacobsen, E. N., Pfaltz, A., and Yamamoto, H., Eds.Springer:Heidelberg, 1999; pp833−886.

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