Comparison of the C−H Activation of Methane by M(C5H5)(CO) for M = Cobalt, Rhodium, and Iridium
Author:
Affiliation:
1. Contribution from the Department of Physics, University of Stockholm, Box 6730, S-113 85 Stockholm, Sweden
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja952338c
Reference44 articles.
1. Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)
2. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
3. Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex
4. Activation of methane by iridium complexes
5. Mechanism of arene carbon-hydrogen bond activation by (C5Me5)Rh(PMe3)(H)Ph. Evidence for arene precoordination
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