W2Cl4(NR2)2(PR‘3)2 Molecules. 7. Preparation, Characterization, and Structures of W2Cl4(NHR)2(NH2R)2 and W2Cl4(NHR)2(PMe3)2 (R = sec-Butyl and Cyclohexyl) and 31P{1H} NMR Studies of Trans-to-Cis Isomerizations of W2Cl4(NHR)2(PMe3)2-Reference-Cited by-同舟云学术

W2Cl4(NR2)2(PR‘3)2 Molecules. 7. Preparation, Characterization, and Structures of W2Cl4(NHR)2(NH2R)2 and W2Cl4(NHR)2(PMe3)2 (R = sec-Butyl and Cyclohexyl) and 31P{1H} NMR Studies of Trans-to-Cis Isomerizations of W2Cl4(NHR)2(PMe3)2

Published:1997-07-01 Issue:15 Volume:36 Page:3268-3276
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Cotton F. Albert¹,Dikarev Evgeny V.¹,Wong Wai-Yeung¹

Affiliation:

1. Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, College Station, Texas 77843-3255

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic961485o

Reference14 articles.

1. The W2Cl4(NHCMe3)2(PR 3)2 molecules (R 3=Me3, Et3, Pr n 3, Me2Ph) I. Their isomeric forms, interconversion proeesses, crystalline forms, and detailed molecular structures

2. W2Cl4(NHCMe3)2(PR3)2 Molecules (R3 = Me3, Et3, Prn3, Me2Ph). 2. 31P{1H} NMR Studies of Cis-Trans Isomerizations and Evidence That Suggests an Internal Flip of the W2 Unit

3. Preparation, characterisation, and X-ray crystal structure of [W2Cl4(NHBut)2(NH2But)2]: a triply-bonded ditungsten compound containing t-butylamido ligands

4. Preparation of octachloroditungstate(4-) and several of its derivatives

5. Preparation and characterization of sodium heptachloropentakis(THF)ditungstate(1-). A synthetically useful precursor for X3W.tplbond.WX3 compounds where X = CH2-tert-Bu, NMe2 and O-tert-Bu

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