Kinetic Evidence for Remote π-Aryl Participation in the BF3-Catalyzed Rearrangement of [2 + 2] Photocycloadducts of Diarylhomobenzoquinones with Diphenylacetylene

Author:

Koizumi Takuya1,Harada Kenji1,Mochizuki Eiko1,Kokubo Ken1,Oshima Takumi1

Affiliation:

1. Department of Materials Chemistry, Graduate School of Engineering, Osaka University, Toyonaka, Osaka 560-0043, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference29 articles.

1. (a) Lancelot, C. J.; Cram, D. J.; Schleyer, P. v. R.Carbenium Ions; Olah, G. A., Schleyer, P. v. R., Eds.; Wiley-Interscience, New York, 1972; Vol. 3, Chapter 27, p 1347.

2. (b) Smith, M. B.; March, J.March's Advanced OrganicChemistry; Wiley:  New York, 2001; Chapter 10, p 407.

3. Aryl .pi. participation in additions and solvolyses of endo-3,3-diphenyltricyclo[3.2.1.02,4]oct-6-ene and -oct-6-yl systems

4. Application of the aromatic ring parameter (I ) to solvolyses of β-arylalkyl toluene-p-sulfonates

5. The Substituent Effects on Solvolyses ofthero-2-Aryl-1-methylpropyl Brosylates

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