Bond Activations of PhSiH3 by Cp2SmH: A Mechanistic Investigation by the DFT Method-Reference-Cited by-同舟云学术

Bond Activations of PhSiH3 by Cp2SmH: A Mechanistic Investigation by the DFT Method

Published:2009-06-08 Issue:13 Volume:28 Page:3767-3775
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Perrin Lionel¹,Maron Laurent¹,Eisenstein Odile²,Tilley T. Don³

Affiliation:

1. LPCNO, Université de Toulouse, INSA, UPS, LPCNO, 135 Avenue de Rangueil, F-31077 Toulouse, France, and CNRS, LPCNO, UMR 5215 CNRS-UPS-INSA, F-31077 Toulouse, France

2. Institut Charles Gerhardt, Université Montpellier 2, Avenue E. Bataillon, F-34095 Montpellier, France, and CNRS, Institut Charles Gerhardt, F-34095 Montpellier, France

3. Department of Chemistry, University of California at Berkeley, Berkeley, California 94720-1460

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om900106n

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4. .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds

5. Synthetic Utility of [(C5Me5)2Ln][(μ-Ph)2BPh2] in Accessing [(C5Me5)2LnR]x Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C−H Activation Reactivity

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