Selective Azide Oxidation of 1,2-Bis(diphenylphosphino)benzene and Related Ethylenebis(phosphines) to Asymmetric Multifunctional Phosphorus Ligands and Formation of Rhodium(I) Complexes of These Ligands. Structural Characterization of the Prototypical Ligand 1-(((Trimethylsilyl)imino)diphenylphosphorano)-2-(diphenylphosphino)benzene and Its Rhodium(I) Complex: 1-Ph2PN(SiMe3)C6H4-2-(Ph2P)Rh(CO)Cl
Author:
Affiliation:
1. Department of Chemistry, University of Alberta, Edmonton, AB, Canada T6G 2G2
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9514713
Reference39 articles.
1. Über neue organische Phosphorverbindungen III. Phosphinmethylenderivate und Phosphinimine
2. Heterofunctional Ligands Derived from Monooxidized Bis(phosphino)amines. Synthesis and Transition Metal (Rh(I), Pd(II), Pt(II)) Complexes of the Triphosphorus Ligands ((Iminophosphoranyl)amino)phosphine Phosphinic Oxides Ph2PN(R)Ph2P:NP(O)(OPh)2 (R = CH3, C2H5). Crystal and Molecular Structures of the Rhodium(I) and Platinum(II) Complexes (PhO)2(O)PN:PPh2N(C2H5)Ph2PRh(CO)Cl and (PhO)2(O)PN:PPh2N(C2H5)Ph2PPtCl2
3. Heterodifunctional ligands derived from monooxidized bis(phosphino)amines. Synthesis and transition metal (molybdenum(O), tungsten(O), rhodium(I), palladium(II), and platinum(II)) complexes of (diphenylphosphino)(diphenylphosphinothiolyl)- and (diphenylphosphino)(diphenylphosphinoselenoyl)phenylamine, Ph2PN(Ph)P(E)Ph2 (E = S, Se). Crystal and molecular structure of the Pt(II) complex [Cl2Pt(PPh2N(Ph)P(S)Ph2].cntdot.H2O
4. Heterobifunctional Phosphorus-Nitrogen Compounds: Iminophosphoranophosphines and Their Complexes
5. Functionalized phosphine-phosphinimines as heteroatomic ligands. Synthesis, characterization, and representative x-ray structures of the phosphine-phosphinimines Ph2PCH2PPh2:NAr [Ar = 5-F,2,4-(NO2)2C6H2, 4-(CN)C6F4] and structure of the rhodium(I) complex Cl(CO)RhP(Ph)2CH2PPh2:NC6F4-4-CN
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