Structural, Spectroscopic, and Electrochemical Studies of the Complexes [Ni2(μ-CNR)(CNR)2(μ-dppm)2]n+ (n = 0, 1, 2): Unusual Examples of Nickel(0)−Nickel(I) and Nickel(0)−Nickel(II) Mixed Valency-Reference-Cited by-同舟云学术

Structural, Spectroscopic, and Electrochemical Studies of the Complexes [Ni2(μ-CNR)(CNR)2(μ-dppm)2]n+ (n = 0, 1, 2): Unusual Examples of Nickel(0)−Nickel(I) and Nickel(0)−Nickel(II) Mixed Valency

Published:2004-01-07 Issue:3 Volume:43 Page:1071-1081
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Ferrence Gregory M.¹,Simón-Manso Eugenio¹,Breedlove Brian K.¹,Meeuwenberg Leah¹,Kubiak Clifford P.¹

Affiliation:

1. Department of Chemistry & Biochemistry, University of California San Diego, La Jolla, California 92093-0358, and Department of Chemistry, Illinois State University, Normal, Illinois 61790

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic035021j

Reference42 articles.

1. Binuclear complexes of nickel(0): comparison of a bridging methyl isocyanide and a bridging (methylamino)carbyne ligand

2. Role of bridging ligand .pi.-acidity in determining the nature of the lowest excited states of binuclear complexes of nickel(0). Ligand-centered (M2 .fwdarw. .mu.-LCT), metal-centered (.mu.-L .fwdarw. M2CT), and intraligand (IL) lowest excited states for the series of complexes Ni2(.mu.-L)(CNMe)2(PPh2CH2PPh2)2 (L = CNR, CNMe(R)+, NO+)

3. Carbon dioxide chemistry and electrochemistry of a binuclear cradle complex of nickel(0), Ni2(.mu.-CNMe)(CNMe)2(PPh2CH2PPh2)2

4. Carbon dioxide induced metathesis of CN and CO triple bonds of methyl isocyanide and carbon monoxide

5. Nickel-nickel dimers: the synthesis and novel structure of [Ni2(.mu.-CNMe)(CNMe)3(PPh2CH2PPh2)2][PF6]2

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