Solvent Effects on the Reaction Coordinate of the Hydrolysis of Phosphates and Sulfates: Application of Hammond and Anti-Hammond Postulates to Understand Hydrolysis in Solution-Reference-Cited by-同舟云学术

Solvent Effects on the Reaction Coordinate of the Hydrolysis of Phosphates and Sulfates: Application of Hammond and Anti-Hammond Postulates to Understand Hydrolysis in Solution

Published:2001-11-01 Issue:47 Volume:123 Page:11755-11763
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Lopez Xabier¹,Dejaegere Annick¹,Karplus Martin¹

Affiliation:

1. Contribution from the Kimika Fakultatea, Euskal Herriko Unibertsitatea, P.K.1072, 20080 Donostia, Spain, Laboratoire de Chimie Biophysique, Institut le Bel, Université Louis Pasteur, 67000 Strasbourg, France, Oxford Centre for Molecular Sciences, New Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, United Kingdom, Laboratoire de Biologie et Génomique Structurales, Ecole Supérieure de Biotechnologie de Strasbourg, 67400 Illkirch, France, Department of Chemistry and Chemical Biology, Harvard...

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja010683y

Reference41 articles.

1. Unifying the Current Data on the Mechanism of Cleavage–Transesterification of RNA

2. Influence of strain on hydrolysis of five-membered sulfate and phosphate esters

3. Mechanisms of Reaction of Sulfate Esters: A Molecular Orbital Study of Associative Sulfuryl Group Transfer, Intramolecular Migration, and Pseudorotation

4. Stote, R. H.; Dejaegere, A.; Karplus, M. Molecular Mechanics and Dynamics Simulations of Enzymes. Computational Approaches toBiochemical Reactivity; Náray-Szabó, G., Warshel, A., Eds.; Kluwer Academic: Boston,1997; Chapter 4, pp 153−198.

Cited by 53 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. An approach to Hammond’s principle through Kullback–Leibler’s entropy;Journal of Mathematical Chemistry;2023-11-10

2. The Prominent Motif of the Leaving Group in Chemical and Biological Processes of Phosphonoesters: Understanding the Behavior of V‐type Nerve Agents;ChemistrySelect;2022-09-02

3. Mechanistic Insights into Promoted Hydrolysis of Phosphoester Bonds by MoO2Cl2(DMF)2;Inorganic Chemistry;2021-07-16

4. Phosphoryl Transfer Reaction in RNA: Is the Substrate-Assisted Catalysis a Possible Mechanism in Certain Solvents?;The Journal of Physical Chemistry A;2017-10-26

5. Theoretical studies on the effect of sulfur substitution for the methanolysis of cyclic and acyclic phosphate esters;Computational and Theoretical Chemistry;2014-11