Absolute Rates of the Solution-Phase Addition of Atomic Hydrogen to a Vinyl Ether and a Vinyl Ester:  Effect of Oxygen Substitution on Hydrogen Atom Reactivity with Olefins

Author:

Tanner D. D.1,Kandanarachchi P.1,Das N. C.1,Franz J. A.1

Affiliation:

1. Department of Chemistry, University of Alberta, Edmonton, AB T6G 2G2 Canada, and Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99352

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Reference20 articles.

1. Regioselective Addition of Atomic Hydrogen to Olefins. Reversible 1-Methyl-5-hexenyl Radical Cyclization in the Solution-Phase Hydrogenation

2. Absolute Rate Constants for the Addition of Atomic Hydrogen to Monosubstituted and Trisubstituted Olefins

3. Absolute Rate Constants for Allylic Abstraction of Hydrogen by Atomic Hydrogen

4. Evaluated Kinetic Data on Gas-Phase Addition Reactions:  Reactions ofAtoms and Radicals with Alkenes, Alkynes and Aromatic Compounds; Kerr, J. A., Parsonage, M. J., Eds.; Butterworths:  London, 1972. Weissman, M.; Benson, S. W.Int. J. Chem. Kinet.1984,16, 307. Benson, S. W.Thermochemical Kinetics Methods for the Estimation of ThermochemicalData and Rate Parameters, 2nd ed.; Wiley-Interscience:  New York, 1976; pp 95−96 and references therein.

5. Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution:  New Evidence for Polar Interactions

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