cis-Bis(alkenyl)iridium(III) Compounds by Apparent Insertion of Two Acetylenes into Two Ir−P Bonds: Crystal Structures of cis,trans-[IrCl(−CHCH+PPh3)2(CO)(PPh3)2]2+ and [Ir(OClO3)(CH3)(H2O)(CO)(PPh3)2]+-Reference-Cited by-同舟云学术

cis-Bis(alkenyl)iridium(III) Compounds by Apparent Insertion of Two Acetylenes into Two Ir−P Bonds: Crystal Structures of cis,trans-[IrCl(−CHCH+PPh3)2(CO)(PPh3)2]2+ and [Ir(OClO3)(CH3)(H2O)(CO)(PPh3)2]+

Published:2000-03-24 Issue:8 Volume:19 Page:1572-1577
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Chin Chong Shik¹,Lee Misun¹,Oh Moonhyun¹,Won Gyongshik¹,Kim Mieock¹,Park Young Ja¹

Affiliation:

1. Department of Chemistry, Sogang University, Seoul 121-742, Korea, and Department of Chemistry, Sookmyung Women's University, Seoul 140-742, Korea

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0000459

Reference33 articles.

1. Reaction of an (Alkyl)(alkenyl)(alkynyl)iridium(III) Complex with HCl: Intramolecular C−C Bond Formation from Alkyl, Alkenyl, and Alkynyl Groups Coordinated to “Ir(CO)(PPh3)2”. H/D Exchange between CH3 and DCl

2. Reactions of Iridium(III) Compounds with Alkynes in the Presence of Triethylamine: The First Example of MCHCH+NR3

3. Facile insertion of alkynes into Ir–P (phosphine) and Ir–as (arsine) bonds: second and third alkyne addition to mononuclear iridium complexes

4. Alkyne reactions with rhenium(V) oxo alkyl phosphine complexes - phosphine displacement versus apparent Re-P insertion

5. (e) Corrigan, J. F.; Taylor, N. J.; Carty, A.Organometallics1994,13, 3778, and references therein.

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