Structural Diversity in Lanthanide Phosphido Complexes. Formation and X-ray Crystal Structure Determination of an Unusual Dinuclear Phosphido Complex of Divalent Samarium: [(Me3Si)2P]Sm[μ-P(SiMe3)2]3Sm(thf)3·C7H81
Author:
Affiliation:
1. Anorganisch-chemisches Institut, der Technischen Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om950624r
Reference17 articles.
1. Synthesis and x-ray crystal structure of the divalent [bis(trimethylsilyl)amido] samarium complexes [(Me3Si)2N]2Sm(THF)2 and {[(Me3Si)2N]Sm(.mu.-I)(DME)(THF)}2
2. Low co-ordination numbers in lanthanoid and actinoid compounds. Part 2. Syntheses, properties, and crystal and molecular structures of triphenylphosphine oxide and peroxo-derivatives of [bis(trimethylsilyl)-amido]lanthanoids
3. Three coordination in metal complexes
4. Structure of tris(bis(trimethylsilyl)amido)neodymium(III), Nd[N(Si(CH3)3)2]3
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