Asymmetric Synthesis of the Tricyclic Core of NGF-Inducing Cyathane Diterpenes via a Transition-Metal-Catalyzed [5 + 2] Cycloaddition
Author:
Affiliation:
1. Department of Chemistry, Stanford University, Stanford, California 94305-5080
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol0160699
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1. Synthesis of a chiral rhodium alkyl via metal insertion into an unstrained C-C bond and use of the rate of racemization at carbon to obtain rhodium-carbon bond dissociation energy
2. Transition Metal-Catalyzed [6+2] Cycloadditions of 2-Vinylcyclobutanones and Alkenes: A New Reaction for the Synthesis of Eight-Membered Rings
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