Protonation Reactions of trans-M(H)(SPh)(dppe)2 (M = Ru, Os) To Give Thiol and Dihydrogen Complexes. X-ray Crystal Structure Determination of trans-Ru(H)(SPh)(dppe)2 and trans-[Os(H)(O2)(dppe)2](O3SCF3)
Author:
Affiliation:
1. Department of Chemistry, University of Toronto, Toronto, ON M5S 3H6, Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic971050g
Reference31 articles.
1. Synthesis and Characterization of a Stable Iron(II) Hydride-Thiolate Complex: (PhS)Fe(H)(CO)2(P(OPh)3)2
2. Heterolytic Activation of Dihydrogen at Transition-Metal Sulfur Sites in Coordinatively Unsaturated [rh(L)(“buS4”)]BF4 Complexes, Involving Neutral Hydrides, Thiol Hydrides, and Thiol–Hydride Proton Scrambling (L = CO, PCy3; “buS4”2- = 1,2-Bis[(2-mercapto-3,5-di-tert-butylphenylthio]ethane2-)
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